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We have a system all you need to do is execute a system rules. © 2003 CRC Press LLC 79. 30, 177 (2002) 100. 61 3. 2-1 Let Then Subtract, n141 Sn 14aþarþar2 þþarn1 rSn 14 arþar2 þþarn1 þarn ð1 rÞSn 14 a arn Using (1) and (2) in (3), as is expected in the physical system.

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CCCC overlap of orbitals is more efficient in a σ bond than in a π bond C C energy needed to hν promote electron fromπto π CC π antibonding molecular orbital electron promoted to antibonding orbital cancels out electron in bonding orbital result: no π bond π bonding molecular orbital both electrons in π bond RRRRRRRH hν HHHHHHHR no rotation is possible UV light breaks π bond mixture of both isomers formed rotation is now possible Molecules with more than one CC double bond Benzene has three strongly interacting double bonds The rest of this chapter concerns molecules with more than one CC double bond and what happens to the π orbitals when they interact.

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