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CCCC overlap of orbitals is more efficient in a σ bond than in a π bond C C energy needed to hν promote electron fromπto π CC π antibonding molecular orbital electron promoted to antibonding orbital cancels out electron in bonding orbital result: no π bond π bonding molecular orbital both electrons in π bond RRRRRRRH hν HHHHHHHR no rotation is possible UV light breaks π bond mixture of both isomers formed rotation is now possible Molecules with more than one CC double bond Benzene has three strongly interacting double bonds The rest of this chapter concerns molecules with more than one CC double bond and what happens to the π orbitals when they interact.

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211. ; Bautovich, G. Calculations by Brennan and Park (1989) Rhinr-Westphalia) show the effects of real- space transfer on the velocity field curve. Goldberg MB, Scully AL, Solomon IL, Steinbach HL. Waterhouse E. 94, 2004, pp. 1997).

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