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Most of the complexes of titanium(II1) are octahedral and are produced by reacting Tic13 with an excess of the ligand, giving rise to stoichiometries such as [TiL61X3, [TiL4X2lX, [TiL3X3] and Mi[TiX6] (L neutral unidentate ligand, X singly charged anion) (Table 21.

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